You should be able to configure the exchange to be the default mail account in Outlook 2007 which should bring it up automatically upon opening. Here is a rough guide as I do not have Outlook 2007 on this machine or in front of me: Tools>Accounts>Select Exchange>Press Default>Close Outlook>Re-open Outlook.
If you want to open both simultaneously, and just have the mail sorted, you’ll have to run the Rule’s Wizard and configure something like “if recieved by this mail account, place into this folder, on send/receive.”
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