There is no product called “Vm ware XP” or “VMware Windows XP”.
If you are talking about installing VMware, then running a virtual machine which has Windows XP installed on it, yes you can do that. You’ll need VMware Workstation or VMware Server to do that.
Like he said, sure you can do it. Google VMWARE.
Make sure your processor supports the VM instructions and that you have plenty of HDD and memory to support the concurrent running of two OS.
I do and it works great.