On Ubuntu you use CUPS (Common UNIX Printing System) as a printing system. Whatever your Ubuntu session (desktop) manager, you can open CUPS web management interface, just connect with your browser to:
http://localhost:631/ or http://127.0.0.1:631/
delete Pixma MP220 printer there and add new printer using Canon Pixma 258 driver… Drivers, in fact, are intended to be used by printing system, not by other software (e.g., LibreOffice).
And, btw, CUPS web interface is much more robust than printer configuration utilities of the session (desktop) managers, got this impression not only from Ubuntu, but from other distributions too.