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There are a few ways to accomplish this with relative ease.
Depending on the complexity of the XML document the resulting DB table(s) structure will be need to be constructed accordingly.
Good reference to start with is the IBM Redbook The Ins and Outs of XML and DB2 for i5/OS (always plug your own efforts first as they say) and Jon and Susans efforts @ www.partner400.com.
if you wish to contact me offline as well I can help guide you once you provide more information as to what you are trying to accomplish.