That depends on what you want to work on. If you want to be a network engineer then CCNA. If you want to be a Windows Systems Administrator then the MCSE. If you want to be a Linux admin then neither would be correct.
You may want to read the “<a href=”http://itknowledgeexchange.techtarget.com/it-jobs/why-entry-level-certs-arent-enough-to-get-you-a-job/”>Why Entry-Level Certs Aren’t Enough to Get You a Job</a>” blog post on the “<a href=”http://itknowledgeexchange.techtarget.com/it-jobs/”>IT Career JumpStart</a>” blog.